by Beth Mundy, Pacific Northwest National Laboratory
High-precision synthesis and measurements of oxide thin films helped researchers determine how iron affects the way the material functions, for instance in its ability to convert water to oxygen in a fuel cellCredit: Timothy Holland | Pacific Northwest National Laboratory Without thin films, there would be no modern electronics or high-quality mirrors
The semiconductor chips used in our cell phones and computers rely on thin films made of different materials, including metal oxides that contain at least one metal as well as oxygen
Metal oxide thin films serve as more than just a layer within electronics
They have applications in sensing, catalysis, and energy storage
Creating thin films that can replace the liquid layer in batteries or promote specific chemical transformations requires understanding the materials at an atomic level
At Pacific Northwest National Laboratory (PNNL), researchers are looking into how to design metal oxide thin films that can be harnessed to produce clean energy
"I like to think of what we do as spray painting a target with atoms," said PNNL materials scientist and Laboratory Fellow Scott Chambers
His team uses a technique, called molecular beam epitaxy, for depositing elements atom by atom on top of a solid crystal
This enables researchers to make high-quality, crystalline thin films with precise control over their composition and structure
For example, some thin films always conduct electricity and others do not
By stacking different films, scientists can change how they respond to an electrical current
"Our ability to develop advanced energy technologies depends on how well we can make thin layers of materials," said Peter Sushko, a materials scientist at PNNL
Making extremely thin oxide films with high precision requires advanced synthesis equipment
This equipment is moving to a new and larger laboratory in PNNL's Energy Sciences Center (ESC)
The Atomically Precise Materials team currently uses two molecular beam epitaxy systems and one pulsed laser deposition instrument
The planned addition of another pulsed laser deposition instrument will expand the team's capacity to create more and different experimental thin films
Small changes in thin films have significant impacts Le Wang, a PNNL materials scientist, led a recent study that harnessed atomically precise thin films to make stable high-performance catalysts
They discovered that varying the composition of lanthanum nickel iron oxide (LaNi1-xFexO3 or LNFO) thin films affects their ability to convert water into oxygen
This reaction is important for clean energy production
LNFO has the potential to reduce the need for or replace expensive precious metal-based catalysts
Previous research demonstrated that replacing some of the nickel with iron in lanthanum nickel oxide increases the material's ability to generate oxygen
However, the exact reason for this enhanced activity was unclear
Le Wang uses an X-ray photoelectron spectroscopy instrument to measure the composition and electronic structure of synthesized thin films
Credit: Andrea Starr | Pacific Northwest National Laboratory The PNNL research team used its high-precision films and instrumentation to address this uncertainty
The work, published in Nano Letters, provides clear evidence and explanations for why mixing nickel and iron leads to more efficient oxygen formation
The PNNL researchers synthesized a series of high-quality LNFO thin films, from pure lanthanum nickel oxide to lanthanum iron oxide and a range of compositions in between
They also made several high-quality standards, all measured with the same equipment, that enabled researchers to home in on small, but consequential, changes in the electronic structure of the materials
The small changes showed the iron transferring some of its electrons to the nickel in a process known as charge transfer
The charge transfer makes it easier for the material to convert water to oxygen
Identifying this previously unseen charge transfer gave researchers insight into why LNFO acts as a better catalyst
Modeling for atomic-scale understanding The team uses a multi-pronged approach in its research
They synthesize new materials and characterize their structure in the laboratory
However, benchtop experiments have limits to how much detail they can reveal
The team's not-so-secret weapon? Theory
Combining theory and experiments generates deeper insights into oxide thin films
Computational modeling provides insight into how atoms move on the film surface and how electrons rearrange at scales smaller than the diameter of an atom
In this project, the researchers wanted to see if atoms in simulated LNFO showed the same subtle signs of charge transfer that they observed in the lab
"It was an exciting day when we got Peter [Sushko]'s calculations back and they matched our experimental data so well," said Wang
"Those results really validated our argument about the importance of charge transfer in LNFO
" Looking to the future of thin films This research will continue at the ESC, where large windows will spotlight a new high-visibility lab space
Anyone who comes into the ESC lobby will be able to see the researchers making new samples
"We're excited for the window into our science the move will provide for visitors to the ESC," said Sushko
"In addition to the larger laboratory and additional instrumentation, we're all looking forward to being together in the same building
" Up next? The researchers plan to partially replace lanthanum with strontium in the same film system, creating an oxide with four different metals
This will help the team further understand changes in the structures and properties of complex oxide films
Understanding such processes will guide new synthesis efforts to design even better catalysts
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